Empirical Formulas

Nov 17, 2009 at 10:16 PM
Molecular

  • P4O10
  • C10H22
  • C6H18O3
  • C5H12O

  • N2O4
Empirical


  • P2O5


  • C5H11


  • C2H6O


  • C5H12O


  • NO2

-Empirical formulas gives the whole number ratios of elements in a compound
-Molecular formulas give the actual numbers
-therefore, the empirical formula is the simplest form

ex. (in-class) A sample of an unknown compound is analyzed and found to contain 8.4g of C and 2.1g of H, and 5.6g of O.
C8.4H2.1O5.6  <--------- this is wrong because it is not in whole numbers!

Element
Mass (g)
Atomic Mass
Moles
C
8.4
12.0 g/mol
8.4g ÷ 12.0 g/mol = 0.7 mol
H
2.1
1.0 g/mol
2.1g ÷ 1.0 g/mol = 2.1 mol
O
5.6
16.0 g/mol
5.6g ÷ 16.0 g/mol = 0.35 mol

ex. A compound was analyzed and found to contain 13.5 g Ca, 10.8 g O, and 0.675 g H. What is the empirical formula of the compound?


Element
Mass (g)
Atomic Mass
Moles
Ca
13.5
40.1 g/mol
13.5g ÷ 40.1 g/mol = 0.337 mol
O
10.8
16.0 g/mol
10.8g ÷ 16.0 g/mol = 0.269 mol
H
0.675
1.0 g/mol
0.675g ÷ 1.0 g/mol = 0.675 mol

Here's a helpful hint for putting your ratios into whole numbers:
If the ratio ends in... 
~0.5 multiply by 2
~0.33 or ~0.66 multiply by 3
~0.25 or ~0.75 multiply by 4
~0.2, ~ 0.4, ~0.6, ~0.8 multiply by 5


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