Molecule building
| 0 comments |
Esterfication Lab
Here's a quick review if you do not remember how Esterfication works:
| 0 comments |
Amines and Amides
Amines:
end in -amine after the alkyl prefix
have a double bonded oxygen to the carbon chain and NH2 connected to the carbon chain
Name the following:
Answers:
1. ethanamide
2. methanamide
Amides:
end in -amide with the carbon prefix
have possibilities of primary (one carbon chain), secondary (two carbon chains), or tertiary (three carbon chains) chains connected to nitrogen
Name the following:
Answers:
1. dimethylamine
2. methylamine
| 0 comments |
Aldehydes, Carboxylic Acids, Esters & Esterfication
Naming: change the -e ending to -al
Ex. Draw Methanal (formaldehyde)
Ex. Benzaldehyde
CARBOXYLIC ACIDS
Naming: change the ending to -oic acid
Examples:
ESTERS
Naming: the primary chain has the -yl ending and the secondary chain takes the -oate ending
Examples:
ESTERFICATION
Always has H2O
Check out this website for some help!
http://www.ausetute.com.au/esters.html
| 0 comments |
Functional Groups
-halogen atoms replace a hydrogen: Bromo, Chloro, Floro
EX. 2,2, dibromo 3 chloro, 1,3 difloro propane
Alchohols:
-OH or hydroxyl group
-change the ending to -ol
EX. 3 floro 2 methyl 4 pentaol
Ketones:
-oxygen atom doubled bonded to carbon
-change the ending -one
EX. 2 propaone (acetone)
Ethane:
-have an O joingin the two carbon chains together
-name carbon side chain with -yl ending and add 'ether'
EX. diethyl ether
| 0 comments |
Alkenes & Alkynes
- compounds with double bonds end in -ene
- a number in front of the parent chain tells where the double bond is
- more than 1 double bond changes the parent chain slightly
ALKYNES
- for compounds with triple bonds, use the -yne ending
- follow all the same alkene rules
Here's a quick recap:
And for some practice, check out this worksheet:
Organic Chemistry (with answers)
| 0 comments |
Organic Chemistry
- the study of carbon compounds is organic chem
- carbon can have multiple bonds and form many different shapes
Hydrocarbons have 3 types of formulas:
- molecular formulas (C6H14)
- condensed structural formula (CH3-CH2-CH2-CH2-CH2-CH3)
- structural formula
Nomenclature of Hydrocarbons
- One molecular formula can have a number of different structures
- Isomers are compounds that can be drawn in more than one way
How to name alkanes
1) Add "ane" to the longest chain with the correct suffix
2) Locate any branches by number carbon atoms (with the lowest numer)
3) Name branches with the appropriate suffix and -yl ending (Alkyl branches)
4) If there are more than one of the same alkyl group, number each one and add the multiplier number in front of the branch name
| 0 comments |
Ions in Solutions
-solvation is the interaction btw solutes and solvents
-ionic solids (salts) are crystals made up of ions
-molecular solids are cystals made up of neutral molecules
-dissolving ionic solutions produces ions in a process called dissociation
-ionization is the break up of a neutral molecutle into charged particles
EX. CH3COOH--->CH3COO- + H+
-Determining concentrations is relatively easy
EX. What is the [Cl-] in a solution of 0.50M AgCl3
1)AgCl3--->Ag+ + 3Cl-
2)0.50 x 3 = 1.50M
| 0 comments |
Polarity
- non-polar substances have equal charge distribution
- polar substances have unequal charge distribution
- in simpler terms, polarity depends on the symmetry of the structural diagram
Practice Questions: Determine whether each is polar or non-polar.
SiF4
SF4
PCl5
H2O
XeF4
Answers:
Non-polar
Polar
Non-polar
Polar
Non-Polar
| 0 comments |
Intermolecular Bonds
1. London Dispersion Force (L.D.F.)
- results from temporary electron diploes
- weakest intermolecular force
- increases as the number of electrons increases
- occurs in any compound that has electrons (aka EVERYTHING)
2. Dipole-Dipole Force
- results from a permanent dipole in molecules
- polar molecules experience this force
- polarity depends how much elements want electrons (electronegativity)
- the strength of the bond depends on the difference in electronegativity between the two atoms
3. Hydrogen Bonds (H-Bonds)
- this is a special type of dipole-dipole bond between H and O, F, or N.
Looking for a bit more information? Check out this site!
Want some practice? Check out this quiz!
| 0 comments |
DISSOCIATE
- ionic slutions dissociate when placed in water
NaCl(s)--H2O--> Na+(aq) + Cl-(aq)
- molecular solutions do not usually split into ions
C12H22O11(s)--H2O--> C12H22O11(aq)
Follow these steps to determine conductivity:
Is it a metal?
If yes, then its conductive. If no, is it a solid non-metal? If yes, then its non-conductive. If no, is it an acid or base? If yes, then its conductive. If no, is it ionic? If yes, then its conductive and if it's no, then its non-conductive.
| 0 comments |
Review Class
1) Dalton, Thomson, Rutherford, Bohr models
2) Bohr energy level diagrams
3) The differences between ions, atoms, isotopes
4) Atomic Structure (atomic number, atomic mass, number of electrons, etc)
5) Trends on the Periodic Table (mass, charge, ionization energy, size, reactivity)
6) Metals, non-metals, metalloid properties
7) Lewis dot diagrams
8) Structural diagrams
G'luck!
| 0 comments |
Conductivity Experiments
In today's class, we separated ourselves into groups and used a conductivity sensor to determine the conductivity of 9 substances.
Here are my results:
SOLUTION | CONDUCTIVITY | IONIC OR MOLECULAR? | ACID OR BASE?
Acetic Acid | 1518μs/cm | molecular | acid
Hydrochloric Acid | 16650μs/cm | molecular | acid
Hydrogen Sulfate | 32350μs/cm | ionic | acid
Copper Chloric Acid | 4156μs/cm | ionic | acid
Sodium Chloride | 4167μs/cm | ionic | base
Ammonia | 1500μs/cm | molecular | base
Sodium Hydroxide | 3300μs/cm | ionic | base
Sucrose | 0μs/cm | molecular | acid
Ethyl Alcohol | 0μs/cm | molecular | base
Take a look at this video about conductivity and pH:
| 0 comments |
Covalent/Double/Triple Bonds
-electrons are shared between non-metals
-to draw Lewis Dot Diagram:
1. Add the valence e- in all atoms
2. Identify which atom can form the most number of bonds. This will be the central atom
3. Bonds between two atoms are represented by a e-. This represents 2e-
4. Any e- not creating bonds are placed in pairs around the remaining atoms
5. All valences levels must be filled, all electrons must be used
Double and Triple Bonds
- some compounds from more than one bond between two elements
http://www.youtube.com/watch?v=tOpke6cpqWY&feature=pyv&ad=4006919948&kw=covalent%20bonds
http://www.youtube.com/watch?v=mAjrnZ-znkY
Electronegativity
- atoms affinity for electrons
- electronegativity increase from left to right and from bottom to top
| 0 comments |
Atoms and Ions
-# of protons = # of electrons
-ions have different # of protons and electrons
-ions cane either be positive (lost e) or negative (extra e)
-cation = positive ion
-anion = negative ion
EX. Determine how many electrons each of the ions have. What type of ion are they(cation/anion)?
-Ca2+ lost 2e, cation, 18e
-Ag+ lost 1e, cation, 46e
EX. Determine how many protons,neutrons,electrons the following substances have.
-76As3- p=33 n=43 e=36
-201Au+ p=79 n=122 e=78
Bohr Diagrams for Ions
-energy level bohr diagram
8e <--- Ca+ 8e 2e 40Ca 20 Chemical Bonds
-a bond is an electrostatic attraction between particles
-bonds occur as elements try to achieve noble gas electron configuration
---> noble gases (usually) dont form compounds/bonds
---> in noble gasese the outermost energy level have stable octets
-metals lose electrons (oxidize)
-non-metals gain electrons (reduced)
Lewis Dot structure
-atoms can be repersented by dot diagrams
---> dots represent electrons
---> only valence electrons shown
-write the atomic symbol for the atom
---> this represents the nucleus and filled inner electrons levels
-one dodt is used to represent outer energy level elctrons
---> one e is placed in each orbital before any pairing occurs
---> beginning with the 5th e, pairing can occur up to max. of 8e
EX.
Ionic Bond
-electrons are transtered from metal to non-metal
---> no dots are shown on metal
-"charged" species is written in brackets
EX.
| 0 comments |
Trends in Chemical Properties on the Periodic Table
- elements on the left side of the Periodic Table tend to form positive ions (cations)
- elements on the right side of the Periodic Table tend to form negative ions (anions)
- elements are arranged in columns or families by their similar ion charge(s)
- from the left side, elements begin with a positive charge that increases down the right of the period until it reaches a non-metal
- from the right side, elements begin with a negative charge that increases negatively to the left of the period until it reaches a metal
- the transition metals which have been positioned in the center (indicated on the chart by a solid checkered line) because most of them have more than one charge
Chemical Reactivity: the rate at which a chemical substance tends to undergo a chemical reaction time
- for metals, chemical reactivity increases as you move towards the left and down
- for non-metals, chemical reactivity increases as you move towards the right and up
ex. Potassium is more reactive than Beryllium because it is farther to the left and farther down. (Potassium also has much more electrons and is only one electron away from reaching a full valence shell.)
Ionization Energy: the energy needed to remove electrons from an atom; also referred to as ionization potential
- an atom with layers of inner electrons has stronger ionization energy because the inner electrons protect the outer electrons from the force of attraction the protons give off
ex.Chlorine has stronger ionization energy than Lithium
| 1 comments |
Chemical Families
- Hydrogen is its own group
- elements in the same chemical family have similar physical and chemical properties.
Alkali Metals
- in group 1
- highly reactive and reactivity increases as you go down
- have only one electron in their outer shell and are lose that electron in ionic bonding with other elements
- react with non-metal
- usually have lower densities than other metals
- malleable, ductile, good conductors of heat and electricity
- have low melting points, below 200 °C
- soft and can be cut with a knife
Alkaline Earth Metals
- 2nd group
- have two electrons in their outer shell
- have low electronegativities
- less reactive than Alkali Metals but they will burn in air if heated. T
- react with water
- shiny
Transition Metals
- are the 38 elements in groups 3-12 of the periodic table
- are very hard
- have high melting and boiling points
- low ionization energies
- high electrical conductivity
- are malleable, they can be shaped and bent.
The Halogens
- in group 17 of the periodic table
- are highly reactive non-metals with strong and unpleasant odours
- will burn flesh and do not react well with water
- fluorine and chlorine are gases at room temperature, bromine is a liquid and iodine and astatine are solids.
Noble Gases
- group 18
- most stable and unreactive elements
- colourless, odourless gases at room temperature
- have high ionization energies and low boiling points
| 0 comments |
Mendeleev's Periodic Table
- he sawa pattern and left spaces in the table for elements that were undiscovered
- there are 118 elements on the Periodic Table
- 7 periods and 18 columns
- metals on the left and non-metals are on the right
- elements with similar properties are in the same vertical column
- Atomic Number: Number of protons of the nucleus of each atom of an element
- Atomic Mass: Mass of an average atom of an element (tends to increase along with atomic number)
- Ion charge: Electric charge that forms on an atom when it gains or loses electrons
| 0 comments |
Where's Mr. Doktor?
Just a quick recap:
This is how two isotopes of hydrogen would look like. In essence, most of their properties are retained except for certain structural details.
| 0 comments |
Emission Spectra
-these are known as emission spectra, unique to each element
-If electrons absorb energy they can bumped to a higer level
-when the fall to a lower level, they release energy as light
Atomic Structure:
-atoms are made up parts called subatomic particles:
1)protons- positive, mass 1, located in nucleus
2)neutrons- neutral, mass 1, located in nucleus
3)electrons- negative, mass 1/1837, located outside
Atomic Number:
-atomic number is the number of protons
Isotopes:
-the number of protons dertermine they type of element
-changing number of neutrons chages isotopes of the element
-all isotopes have the same chemical properites
Mass Number:
-mass number is the total number of protons and neutrons
-give symbol A
-different isotopes have different masses
-mass number = atomic number + number of neutrons
-A = Z+N
| 0 comments |
Bohr Model
-two different models can be used to describe electron configuration
i) Energy Level Model
ii) Bohr Model
-Electrons occupy or orbitals
i) 2 e in the first orbital
ii) 8 e in the second orbital
iii) 8 e in the third orbital
- these are called octet
Hybridized Orbitals
- the first of the Bohr Levels is the 1s-orbital and it holds 2e-
- the second level contains the 2s, 2px, 2py, 2pz orbitals. They combine (hybridize) to from one 2sp3 orbital
| 0 comments |
Early Atomic Theory
Some important points..
The Greeks:
- in 3000 BC, Democritus said that atoms were indivisible particles
- first mention of atoms
- only a conceptual model
- was the accepted view for over 2000 years
Lavoisier:
- Law of conservation of mass
- Law of definite proportions
*wasn't a true atomic theory because it did not discuss what atoms were or how they were arranged
Proust:
- if a compound is broken down into its constituents, the products exist in the same ratio as in the compounded form
- experimentally proved Lavoisier's Laws
Dalton:
- atoms are solid, indestructible spheres (like billiard balls)
- provides for different elements
J. J. Thompson:
- used the raisin bun model
-solid, positive spheres with negative particles embedded in them
- first atomic theory to have positive (protons) and negative (electron) charges
- introduced the idea of nucleus
Rutherford:
- showed that atoms have a positive, dense center with electrons outside it
- resulted in a planetary model
- explains why electrons spin around nucleus
- suggests atoms are mostly empty space
- should be unstable (electrons and protons should attract and destroy the atom)
Bohr:- electrons must only exist in specific orbitals around nucleus
- explains how valence electrons are involved in bonding
- explains the difference between ionic and covalent bonding
- resolves the problem of atomic instability
- includes the neutron (discovered in 1932)
- explains atomic emission spectra
Review Questions:
1. Who first mentioned atoms? Democritus
2. Who introduced the idea of nucleus? J. J. Thomson
3. Who stated that atoms were indestructible? Dalton
4. Who explained bonding and 'levels' around the nucleus? Bohr
5. Who explained why electrons spin around the nucleus? Rutherford
| 0 comments |
Last class of February!
| 0 comments |
Mass 2 Mass!
Lead (IV) nitrate reactions with 5.0 g of Potassium iodide.
Grams of Lead (IV) Nitrate are required?
Pb(NO3) + 4 KI -----> 4 KO3 + PbI45.0 g x 1 mol KI/165.9 g x 1 Pb(NO3)4/4KI x 455.2/ 1 mol Pb(NO3)4 = 3.4 gif a 100 mL solution of 2.0 M H2SO4 is neutralized by sodium hydroxide what mass of water is produced?
H2(SO4) + NaOH -----> HOH + Na2(SO4)2.0 mol/L x .1 L = .200 mol H2(SO4) x 2 HOH/1 H2(SO4) x 18.0 g/mol = 7.2 g H2OPercent Yield
The theoretical yield of the reaction is the expected *calculated* amount. The experimental amount is the actual yield% yield = actual/theoretical x 100
IE: He production of urea CO(NH2) is given by:
2NH3 + Co2 -----> CO(NH2) + H2O. 47.7 g of urea are produced when 1 mole of CO2 reacts, find the actual yield, theoretical yield and percent yield.
The actual yield is 46.7 g.
The theoretical yield: 1 mol CO2 x 1 CO(NH2)2/1 CO2 x 60.1 g/ 1 mol = 60.1 g
Percent Yield = 47.7 g/60.1 g x 100 = 79.4%
| 0 comments |
Limiting Reactants
-one reactant is completely consumed
-this determines how much product is produced
-'Guess' which reactant is limiting, and check how much of it is required
What is thelimiting reactant when 125g of P4 reacts with 323g of Cl2 to form phosphorous tricholoride?
1. P4+6Cl2--->4PCl3
2.125g X 1mol/124g X 6mol of Cl2/1mol P4 X 71g/mol = 431g of Cl2
3. Cl2 is the limiting reactant
Deternmine the theoretical yield of the previous equation
323g X 1mol Cl2/71g X 4mol PCl3/6mol CL2 X 137.4g/1mol PCl3 = 417g
Here's a link for more info on limiting reactants:
http://www.chem.tamu.edu/class/majors/tutorialnotefiles/limiting.htm
| 0 comments |
Stoichiometry Lab
The Experimental Design: 2.00 g of Strontium nitrate is dissolved in 50mL of water and then reacted with excess Copper (II) sulphate (3.00g). The product is a precipitate (Strontium sulphate and Copper (II) nitrate. After mixing the solutions, the precipitate will be seprated by filtration, dried and weighed.
My group's prediction results:
1. What is the balanced chemical equation for this reaction?
Sr(NO3)2 + CuSO4 --> SrSO4 + Cu(NO3)2
2. If 2.00 g of Strontium nitrate completely reacts, how many grams of Strontium sulphate should be produced?
2.00 g Sr(NO3)2 x (1 mol/211.6g) x (1 mol/SrSO4/1 mol Sr(NO3)2) x 183.7g/mol = 1.74 g
We completed the first part of the lab (dissolving the chemicals, forming a precipitate, and seprating it through filtration) and the second half (drying and weighing) will occur next class.
| 0 comments |
MORE STOICHIOMETRY!
O2+2NO >>> 2NO
2.0gx (1 mol of O2/32.0g) x (2mol NO2/1mol O2) = 0.125 mol of NO2
Ex. If 3.0g of O2 with nitrogen monoxide, what volume of nitrogen dioxide is produced at STP?
1. O2 + 2NO2 >>> 2NO2
2. 3.0g x (1mol O2/ 32.0g) x (2mol NO2/1mol O2) x (22.4L/mol) = 4.2L
Ex. In the formation of Copper(II) Oxide, 4.0g of copper react. How many moles of copper oxide are produced?
1.2Cu + O2 >>> 2CuO
2. 4.0g x (2 Cu/63.5g) x (2mol of CuO/ 2mol Cu) = 0.126 mol CuO
Ex. What mass of water is produced when 5.5L of hydrogen is burnt(reacted w/O2)?
1. 2H2 + O2 >>> 2H2O
2. 5.5L x ( mol/22.4) x (18.0g/mol) = 4.4 g
Ex. Lead (IV) Nitrate reacts with 2.0g of potassium iodide. How many moles of leader (IV) nitrate are needed?
1. Pb (NO3)4 + 4KI >>> PbI4+ 4KNO3
2. 2.0g x (1mol PbI4/ 714.8g) x (1 mol Pb(NO3)4/ 1mol PbI4) = 2.8x 10-3 mol
| 0 comments |
Stoichiometry
-Also conversion factors
Ex. (In class) If a 0.15 mole sample of methane reacts with oxygen. How many moles of each product are produced?
1)CH4+2O2--->CO2+2H20
2)0.15molCH4 x 1molCO2/1molCH4 = 0.15 mol CO2
3)0.15molCH4 x 2molH2O/1molCH4= 0.30 mol H20
-Always what you need/what you know
-Converting to mass requires one addtional step
Ex. (In class)How many grams of Bouxite are required to produce 3.5 mol of Al?
1) 3.5molAl x 2molAl2O3/4molAl = 1.75 mol Al2O3
2) 1.75mol x102g/1mol=178.5g
| 0 comments |
Clamps, cans, and candles
Questions from the homework:
1. A car engine burns 250g of octane (C8H18). If 1.19x10^3 kJ of heat are produced, what is the molar enthalpy of the combustion of Octane?
Answer: 250g ÷ 114g/mol (of Octane) = 2.19 mol
1.19x10^3 kJ ÷ 2.19 mol = 543 kJ/mol
4. When ethanol C2H5OH is burned, heat is released. For every mole of ethanol burned, 1300 kJ of heat are released.
a) If 2.5g of ethanol are burnt, how much heat will be released?
Answer: 2.5g x mol/46g x 1300kJ/mol = 70.65 -> 71 kJ
Questions for practice:
ex. What is the molar enthalpy of CO2 (g) in the reaction for the burning of butane below?
2 C4H10 (l) + 13 O2 (g) 8 CO2 (g) + 10 H2O (g) H = -5315 kJ
Answer: Molar enthalpy, change in H = 5315 kJ ÷ 8 mol = 664 kJ / mol.
| 0 comments |
"What? You're in a tree?" "No silly! CALORIMETRY!"
To measure heat absorbed/released by water we need to know THREE important things
1) Temperature change ( 'C)
2) Amount of water (g,kg, mL, L)
3) Specific heat capacity (KJ/ Kg 'C)
deltaH= mCdeltaT
m= mass of water
C= specific heat capacity
deltaT= change of temperature *liquid water is 4.19 KJ/Kg '
MOLAR ENTHALPY
Heat obsorbed/ realeased by one mole
When a candle (C H ) is burnt, heat is released according to reaction"
25 52
C H + 380 ---> 25CO + 26H O+ 11000 KJ
25 52 2 2 2
ex. 9.0 grams of charcoal were completely consumed in a bomb calorimeter. If 2.0 L of water absorbed all of the heat released by the charcoal, and if the temperature of the water increased from 20.25 to 56.04oC, what is the molar enthalpy of carbon?
Answer: deltaH= mCdeltaT
= 2000g(4.19 J/(g C))(56.04-20.25)
= 299 920 J
dH = - C = - 299 920 J = -299.92 kJ
n = 9.0g / 12.01 g/mole = 0.7493 mole
DH/n = -299.92 kJ/ 0.7493 mole = -400.27kJ/mole of C = - 4.0 X 102 kJ/mole
| 0 comments |
Heat And Entalphy
- Rxns that absorb heat are endothermic (cold)
Heat is a form of energy
All chemicals have energy stored in them. Stored chemical energy is called enthalpy.
Enthalpy is stored chemical energy.
Enthalpy of gasoline > Enthalpy of water
Exothermic rxns convert enthalpy into heat.
2C8H18 + 25O2 >>> 16CO2 + 18 H2O + Heat
high enthalpy low enthalpy
Enthalpy has a symbol H
Change in enthalpy is Delta H (triangle H)
Exothermic
- delta H is negative
- products are lower than reactants
- heat is released
Endothermic
- delta H is positive
- reactants are lower than products
- heat is absorbed
Delta H and Moles
coefficients can stand for moles or molecules
| 1 comments |
The 6 Different Chemical Reactions
2Al+3F2--->2AlF3
2)Decomposition
*always assume the products are elements*
4H3PO4--->6H2+P4+8O2
3)Single Replacement
*compounds must always have a metal and a nonmetal*
3Mg+2Al(NO3)3--->2Al+3Mg(NO3)2
4)Double Replacement
MgCl2+K2SO4--->MgSO4+2KCl
5)Neutralization
*Between acids and bases*
*always forms H2O*
H2SO4+2KOH--->2H2O+K2SO4
6)Combustion (burning)
2Mg+O--->2MgO --Metallic
CH4+2O2--->CO2+2H20 --Hydro carbon
| 0 comments |
Balancing with C, H, and O
ex. (in-class) CH4 + 02 -> CO2 + H2O
becomes CH4 + 202 -> CO2 + 2H2O
Also, we found out that we could use fractions while balancing equations. Because the number in front of the atom or compound says how many moles of it there is, it is possible to have a fraction as there can be 1/2 or 7/2 of a mole.
ex. (in-class) C8H18 + O2 -> CO2 + 9H2O
becomes C8H18 + 25/2 O2 -> 8 CO2 + 9H2O
Briefly, we discussed alcohols.
CH3OH - methanol
C2H5O5 - ethanol
In addition, we were given a number of acids we should know.
Hydrochloric acid (HCl)
Nitric acid (HNO3)
Sulfuric acid (H2SO4)
Phosphoric Acid (H3PO4)
Acetic Acid (CH3COOH)
Try some for yourself!
1. CO2 + H2 -> CH4 + H2O
2. C2H6 + O2 -> CO2 + H2O
Answers:
1. CO2 + 4H2 -> CH4 + 2H2O
2. 2C2H6 + 7O2 -> 4CO2 + 6H2O
Need to some more help or examples? Check out the videos below:
| 0 comments |